Chọn đáp án A

Ta có

Bài 2 : 

a)

$Mg + 2HCl \to MgCl_2 + H_2$
$2Al + 6HCl \to 2AlCl_3 + 3H_2$
$n_{H_2} = \dfrac{5,6}{22,4} = 0,25(mol)$
$n_{HCl} = 2n_{H_2} = 0,5(mol)$
$m_{HCl} = 0,5.36,5 = 18,25(gam)$

b)

Bảo toàn khối lượng : 

$m_A = 22,85 + 0,25.2 - 18,25 = 5,1(gam)$

Gọi x,y lần lượt là số mol của Al, Fe

n_H2 = \(\dfrac{8,96}{22,4}\)=0,4 mol

Pt: 2Al + 3H₂SO₄ --> Al₂(SO₄)₃ + 3H₂

......x.................................0,5x...........1,5x

.....Fe + H₂SO₄ --> FeSO₄ + H₂

.......y..........................y............y

Ta có hệ pt:

 {27x+56y=11

   1,5x+y=0,4

⇔x=0,2, y=0,1

% m_Al = \(\dfrac{0,2.27}{11}\).100%=49,1%

% m_Fe = \(\dfrac{0,1.56}{11}\).100%=50,9%

m_Al2(SO4)3 = 0,5x . 342 = 0,5 . 0,2 . 342 = 34,2 (g)

m_FeSO4 = 152y = 152 . 0,1 = 15,2 (g)

Gọi CTTQ: M_xO_y

Pt: M_xO_y + yH₂ --to--> xM + yH₂O

\(\dfrac{0,4}{y}\)<-------0,4

Ta có: 232,2=\(\dfrac{0,4}{y}\)(56x+16y)

⇔23,2=\(\dfrac{22,4x}{y}\)+6,4

⇔\(\dfrac{22,4x}{y}\)=16,8

⇔22,4x=16,8y

⇔x:y=3:4

Vậy CTHH của oxit: Fe₃O₄

\(H_2S + CuSO_4 \to CuS + H_2SO_4\)

\(n_{H_2S} = n_{CuSO_4} = \dfrac{800.1,2.10\%}{160} = 0,6(mol)\\\)

Gọi : \(\left\{{}\begin{matrix}n_{Fe}=a\left(mol\right)\\n_{Zn}=b\left(mol\right)\end{matrix}\right.\)⇒ 56x + 65b = 37,2(1)

\(Fe +S \xrightarrow{t^o}FeS\\ Zn + S\xrightarrow{t^o}ZnS\\ FeS + 2HCl \to FeCl_2 + H_2S\\ ZnS + 2HCl \to ZnCl_2 + H_2S\\\)

Theo PTHH : 

\(n_{H_2S} = a + b = 0,6(2)\)

Từ (1)(2) suy ra a = 0,2; b = 0,4

Vậy :

\(m_{Fe} = 0,2.56 = 11,2(gam)\\ m_{Zn} = 0,4.65 = 26(gam)\)

\(a)n_{HCl}=0,2.1,5=0,3mol\\ CaO+2HCl\rightarrow CaCl_2+H_2O\\ CuO+2HCl\rightarrow CuCl_2+H_2O\\ \Rightarrow\left\{{}\begin{matrix}2n_{CaO}+2n_{CuO}=0,3\\56n_{CaO}+80n_{CuO}=10,8\end{matrix}\right.\\ \Rightarrow n_{CaO}=n_{CaCl_2}=0,05mol;n_{CuO}=n_{CuCl_2}=0,1mol\\ \%m_{CaO}=\dfrac{0,05.56}{10,8}\cdot100=25,93\%\\ \%m_{CuO}=100-25,93=74,07\%\\ b)C_{M_{CaCl_2}}=\dfrac{0,05}{0,2}=0,25M\\ C_{M_{CuCl_2}}=\dfrac{0,1}{0,2}=0,5M\)

\(CaO+2HCl\rightarrow CaCl_2+H_2O\)

x            2x            x           x 

\(CuO+2HCl\rightarrow CuCl_2+H_2O\)

y             2y            y          y 

\(\left\{{}\begin{matrix}56x+80y=10,8\\2x+2y=0,2.1,5=0,3\end{matrix}\right.\)

\(\Rightarrow x=0,05;y=0,1\)

\(a,\%m_{CaO}=0,05.56:10,8.100\%=25,93\left(\%\right)\)

\(\%m_{CuO}=100\%-25,93\%=74,07\%\)

\(b,C_{M\left(CaCl_2\right)}=\dfrac{0,05}{0,2}=0,25\left(M\right)\)

\(C_{M\left(CuCl_2\right)}=\dfrac{0,1}{0,2}=0,5\left(M\right)\)